Try an obtain "Steam, it's generation and uses" by Babcock and Wilcox. This is a very thick, well written book that has more information than you'd think possible about water's phases, how to make efficient boilers and turbines (and nuclear reactors). It's "the bible" of the field, or nearly. They print a new version every few years, but not much really changes in that business, so the older ones are good.
Remember, at 99c water still has
significant vapor pressure. To really get it to act like water ~20 mbar at room temp), you gotta cool it way down below the boiling point. This might figure into your efficiency calx.
I also have a couple of really cool old engineering books from the era when steam was "it" - lighting was all carbon arc (very clever rod feeder designs too) - but sadly, it's way too much to scan. Details of steam engine efficiency are worried to death in these books, with long pedantic arguments about how this or that design of valving gets the most, and how many stages are best (yes, there were multi stage piston steam engines and they actually did get better efficiency). If I can put my hands on a few relevant pages, I'll scan those.
But go ahead and buy the B&W book (used, of course, they show up often that way, but are over $100 new) - you'll be amazed how much there is to know on this topic - it's not just the physics in the usual oversimplified theories - it's the entire shebang and includes all the nasty details from all the loss sources - and there are quite a few you might not have thought of.
For quite awhile, and maybe still - the idea of a steam engine made of modern parts - say stainless steel air-hydraulic cylinders - has attracted me. Say a 3 cyl radial (guaranteed to be self starting). We have stainless and teflon - they had cast iron and horse hide piston rings. Surely we can do better than they did, and they did really well.
http://www.amazon.com/s/ref=nb_sb_ss_i_ ... Caps%2C310
Found a few used copies.
Posting as just me, not as the forum owner. Everything I say is "in my opinion" and YMMV -- which should go for everyone without saying.